1. Joe Gans. The Old Master is credited with inventing the jab.
2. Benny Leonard. The Ghetto Wizard had more than one jab that he used for different purposes.
3. Tommy Loughran. The Philly Phantom was revered for his great left jab.
4. Larry Holmes. No heavyweight had the combination of speed and power like Larry's.
5. Joe Louis. Louis threw precision punches and his jab was fast and powerful.
6. Marvin Hagler. Threw a vicious jab from a southpaw stance packing great velocity.
7. Muhammad Ali. Great foot and hand speed. Threw lightnng fast rapier jabs and rarely missed.
8. Sonny Liston. Sonny smashed teeth with his vicious left jab.
9. Thomas Hearns. Learned his from the Kronk Gym. It was wicked and created openings for his right hand.
10. Oscar De La Hoya. Oscar was a tremendous boxer and had a beautiful jab as you say.
Don't listen to these morons saying Klitschko. Boxing is not what it used to be and modern fighters are all criminals. To answer your question correctly, Ali had the best jab of all time. By definition, a jab is not the knockout punch. Usually knockouts are caused by a series of jabs. Ali was a master at this and beat many opponents this way.
The best I have seen during my time belongs to Wladimir Klitschko, Thomas Hearns and Oscar DLH, agreed there. Also Ricardo Lopez had an incredible technical jab and doesn't get the credit he deserves for it.
Larry Holmes. His jab had the quickness of Ali's and the power of Liston's.
Heavyweights----------------Larry Holmes/ Muhammad Ali
Cruiserweights---------------James Toney/ David Haye
Light Heavyweights---------Michael Spinks/ Joey Giardello
Super Middleweights-------Joe Calzhage/ Roy Jones Jr.
Middleweights-----------------Carlos Monzon/Bernard Hopkins? Sergio Martinez
Super Welterweights--------Thomas Hearns/Winky Wright
Welterweights------------------Sugar Ray Leonard/Sugar Ray Robinson?Floyd Mayweather
Super Lightweights-----------Oscar de la Hoya/ Antonio Cervantes/Nicolino Locche
Lightweights---------------------Perne... Whiatker/ Roberto Duran/Ismael Laguna
Super Featherweights-------Julio Cesar Chavez/Hector Camacho/ Flash Elorde
Featherweights-----------------Salvado... Sanchez/Willie Pep/Henry Armstrong
Super Bantamweights-------Wilfredo Gomez/ Erik Morales/Marco Antonio Barrera
Bantamweights-----------------Eder Joffre/ Orlando Canizales/ Manuel Ortiz
Super Flyweights--------------Kaossay Galaxi
Flyweights------------------------Jimm... Wilde/Jung Koo Chang/Pone Kingpetch
Junior Flyweights--------------Ivan Calderon/Ricardo Lopez
Wladmir Klitschko, Lennox Lewis, Thomas Hearns ,and Yeah De La Hoya.
Larry Holmes had as good a jab as any heavyweight ever, he won and defended many title fights with his jab.
Anderson "THE SPIDER" Silva.
i think oscar de la hoya had a beautiful jab. didn't seem like he was really ever to confident with but when he used it,it was work of art. winky wright had a good quick jab that he used often ,idk which fighters you think had the best jabs of all time